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Is union a Scrabble word?
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- Scrabble US/Canada (OTCWL) Yes
- Scrabble UK (SOWPODS) Yes
- Wordle Yes
- Words With Friends Yes
Scrabble US/Canada (OTCWL) 
Wordle 
Words With Friends What is the meaning of union?
Definition
noun (English)
1. (countable) The act of uniting or joining two or more things into one.Synonyms: junction, coalition, combinationAntonyms: nonunion, disunioncountable
2. (uncountable) The state of being united or joined; a state of unity or harmony.Antonyms: nonunion, disunionuncountable
3. (countable) Something united, or made one; something formed by a combination or coalition of parts or members; a confederation; a consolidated body; a league.countable
4. (countable) A trade union; a workers' union.Examples: "In the autumn there was a row at some cement works about the unskilled labour men. A union had just been started for them and all but a few joined. One of these blacklegs was laid for by a picket and knocked out of time."countable
5. (countable) An association of students at a university for social and/or political purposes; also in some cases a debating body.countable
6. (countable) A joint or other connection uniting parts of machinery, such as pipes.countable
verb (English)
1. (set theory) To combine sets using the union operation.
adj (English)
1. (India) federal.Examples: "The union government of India"India
name (English)
1. (US, with determiner, dated, especially 19th century) The United States of America.Examples: "threats to secede from the Union"USdatedespeciallyobsolete
2. (US, with determiner, historical) Those of the United States that did not secede at the time of the Civil War (of the United States of America).Examples: "Union troops at Gettysburg"UShistorical
3. (with determiner, historical) The Soviet Union: the proper noun Union is the standard English translation of the proper noun Союз (Sojuz), and All-Union is the standard English translation of всесоюзный (vsesojuznyj).Examples: "throughout the Union, but nowhere more so than at the Center [Moscow]"historical
4. (chiefly India, with determiner, law) Alternative form of union.Indiaalt-ofalternative
name (English)
1. (Oxford University, informal) The Oxford Union (a debating society); not to be conflated with Oxford University Student Union (a students' union).informal
Definition source: Wiktionary